INFRA-RED AND PMR SPECTRA OF SOME ORGANOTIN(4) N,N-DIMETHYLDITHIOCARBAMATES

被引：98
作者：
HONDA, M
KOMURA, M
KAWASAKI, Y
TANAKA, T
OKAWARA, R
机构：
[1] Department of Applied Chemistry, Osaka University, Osaka, Higashinoda, Miyakojima
来源：
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1968年 / 30卷 / 12期
关键词：
D O I：
10.1016/0022-1902(68)80117-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Several types of tin(IV) N,N-dimethyldithiocarbamato complexes, Cl2Sn(SSCN Me2)2, Me2Sn(SSCN Me2)2, MeXSn(SSCN Me2)2 (X=Cl, Br, I), and Me2SnX(SSCN Me2) (X=Cl, Br, I) have been prepared. Infra-red and PMR spectra of these complexes have been measured. The results suggest the chelation of dithiocarbamato group. An octahedral trans-configuration have been proposed for Me2Sn(SSCN Me2)2. Configuration of penta-co-ordinated Me2SnX(SSCN Me2) have also been discussed. © 1968.
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页码：3231 / &
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共 21 条
[11]  
HONDA M, 1967, TETRAHEDRON LETT, P3313
[12]  
HONDA M, PRIVATE COMMUNICATIO
[13]   SYNTHESIS AND CONFIGURATIONS OF ORGANOTIN OXINATES [J].
KAWAKAMI, K ;
OKAWARA, R .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1966, 6 (03) :249-&
[14]   SOME PHENYLTIN -LEAD AND -ANTIMONY DITHIOCARBAMATES [J].
KUPCHIK, EJ ;
CALABRETTA, PJ .
INORGANIC CHEMISTRY, 1965, 4 (07) :973-+
[15]  
MAEDA Y, 1966, INORG NUCL CHEM LETT, V2, P197
[16]   SYNTHESIS STRUCTURE AND BONDING OF COMPLEXES OF DIMETHYL- AND DIPHENYLTIN IONS WITH BIDENTATE LIGANDS [J].
MCGRADY, MM ;
TOBIAS, RS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) :1909-&
[17]  
OTERA J, 1967, INORG CHIM ACTA, V1, P294
[18]   MECHANISM OF BENZENE-INDUCED SOLVENT SHIFTS OF PROTON RESONANCES IN NMR SPECTRA [J].
RONAYNE, J ;
WILLIAMS, DH .
CHEMICAL COMMUNICATIONS, 1966, (20) :712-&
[19]   CRYSTAL AND MOLECULAR STRUCTURE OF DIMETHYLTIN BIS(8-HYDROXYQUINOLINATE) [J].
SCHLEMPER, EO .
INORGANIC CHEMISTRY, 1967, 6 (11) :2012-+
[20]   SPALTUNGSREAKTIONEN METALLORGANISCHER VERBINDUNGEN MIT CHALKOGENEN .4. REAKTIONEN VON SCHWEFEL MIT SILICIUMORGANISCHEN, GERMANIUMORGANISCHEN UND BLEIORGANISCHEN VERBINDUNGEN [J].
SCHMIDT, M ;
SCHUMANN, H .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1963, 325 (3-4) :130-138
123