INFRA-RED AND PMR SPECTRA OF SOME ORGANOTIN(4) N,N-DIMETHYLDITHIOCARBAMATES

被引：98

作者：

HONDA, M

KOMURA, M

KAWASAKI, Y

TANAKA, T

OKAWARA, R

机构：

[1] Department of Applied Chemistry, Osaka University, Osaka, Higashinoda, Miyakojima

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1968年 / 30卷 / 12期

关键词：

D O I：

10.1016/0022-1902(68)80117-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several types of tin(IV) N,N-dimethyldithiocarbamato complexes, Cl2Sn(SSCN Me2)2, Me2Sn(SSCN Me2)2, MeXSn(SSCN Me2)2 (X=Cl, Br, I), and Me2SnX(SSCN Me2) (X=Cl, Br, I) have been prepared. Infra-red and PMR spectra of these complexes have been measured. The results suggest the chelation of dithiocarbamato group. An octahedral trans-configuration have been proposed for Me2Sn(SSCN Me2)2. Configuration of penta-co-ordinated Me2SnX(SSCN Me2) have also been discussed. © 1968.

引用

页码：3231 / &

共 21 条

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