2 TRIORGANOSTANNATE COMPLEXES SYNTHESIZED FROM BIS(CYCLOPENTADIENYL)TIN(II) - STRUCTURAL VARIATION BETWEEN [MG(THF)6]2+2[SN(ETA-3-C5H5)3]- AND [LI(THF)4]+[SN(C13H9)3]- (THF = TETRAHYDROFURAN, C13H9 = FLUORENYL)

被引:35
作者
EDWARDS, AJ
PAVER, MA
RAITHBY, PR
RUSSELL, CA
STALKE, D
STEINER, A
WRIGHT, DS
机构
[1] INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY
[2] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 09期
关键词
D O I
10.1039/dt9930001465
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Nucleophilic addition of Mg(C5H5)2 to Sn(C5H5), (1:2) in tetrahydrofuran (thf) gave [Mg(thf)6]2+ 2[Sn(eta3-C5H5)3]2 1 whereas the reaction of fluorenyllithium (2 or 3 equivalents) resulted in nucleophilic substitution of both C5H5 ligands and in the formation of [Li(thf)4]+ [Sn(C13H9)3]- 2; the anion of 1 is essentially planar whereas that in 2 has a distorted-pyramidal structure.
引用
收藏
页码:1465 / 1466
页数:2
相关论文
共 19 条
[1]  
ALLMENNINGEN A, 1967, J ORGANOMET CHEM, V7, P97
[2]   THE OBSERVATION OF A PB-LI BOND - SYNTHESIS, STRUCTURE AND MODEL MOLECULAR-ORBITAL (MO) CALCULATIONS ON THE MONOMERIC PH3PB-LI.(PMDETA) COMPLEX [PMDETA=(ME2NCH2CH2)2NME] [J].
ARMSTRONG, DR ;
DAVIDSON, MG ;
MONCRIEFF, D ;
STALKE, D ;
WRIGHT, DS .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (19) :1413-1415
[3]   ON THE STRUCTURE OF ALKALI-METAL TRIPHENYLSTANNIDE SALTS IN SOLUTION AND IN THE SOLID-STATE [J].
BIRCHALL, T ;
VETRONE, JA .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (13) :877-879
[4]  
Davidson M. G., 1992, ANGEW CHEM, V104, P1265
[5]   [(ETA-5-CP)2SN(MU-ETA-5-CP)NA.PMDETA], A COMPOUND WITH A TRIGONAL-PLANAR PADDLE WHEEL TRIORGANOSTANNATE ION [J].
DAVIDSON, MG ;
STALKE, D ;
WRIGHT, DS .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (09) :1226-1227
[6]   METALATIONS OF 1-AMINONAPHTHALENE WITH ALME3 AND WITH ZNET2 - SYNTHESES AND CRYSTAL-STRUCTURES OF CYCLOBUTANE-LIKE [ME2AL(N(H)NAPHTHYL)]2 AND CYCLOHEXANE-LIKE [ET2N(N(H)NAPHTHYL).THF]3 [J].
DAVIDSON, MG ;
ELILIO, D ;
LESS, SL ;
MARTIN, A ;
RAITHBY, PR ;
SNAITH, R ;
WRIGHT, DS .
ORGANOMETALLICS, 1993, 12 (01) :1-3
[7]   DO SUBVALENT MAIN-GROUP COMPOUNDS FORM ADDUCTS WITH MAIN-GROUP ACCEPTORS - THE BF3 ADDUCT OF STANNOCENE, A REVISION - THE CRYSTAL AND MOLECULAR-STRUCTURE OF ([BF4]-(MU-ETA-5-C5H5)2SN[MU-ETA-5-C5H5SN]+THF)N [J].
DORY, TS ;
ZUCKERMAN, JJ ;
BARNES, CL .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 281 (01) :C1-C7
[8]  
FIESER LF, 1987, REAGENTS ORGANIC SYN, V15
[9]   UBER AROMATENKOMPLEXE VON METALLEN .4. DI-CYCLOPENTADIENYL-BLEI [J].
FISCHER, EO ;
GRUBERT, H .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1956, 286 (5-6) :237-242
[10]  
Harrison PG, 1989, CHEM TIN