A NOVEL ROTATING-DISK ELECTRODE CELL DESIGN - THE INVERTED ROTATING-DISK ELECTRODE

被引：18

作者：

ZDUNEK, AD

SELMAN, JR

机构：

[1] Department of Chemical Engineering, Illinois Institute of Technology, Chicago

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1992年 / 139卷 / 09期

关键词：

D O I：

10.1149/1.2221261

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A new cell configuration for use with the rotating disk electrode (RDE), the inverted rotating disk electrode (IRDE), is outlined. The IRDE faces upwards in solution and rotates without electrolyte leakage, even in highly corrosive solutions. This facilitates gas evolution and free convection studies. Mass transfer characteristics obtained by limiting current measurements agree well with literature for the RDE.

引用

页码：2549 / 2551

页数：3

共 8 条

[1]

Kolthoff I., 1952, TXB QUANTITATIVE INO

[2]

Levich V. G., 1962, PHYSICOCHEM HYDRODYN, P60

[3]

PLESKOV YV, 1976, ROTATING DISC ELECTR, P25

[4] FREE-CONVECTIVE MASS-TRANSFER TO A ROD-SHAPED VERTICAL ELECTRODE [J].

SELMAN, JR ;

TAVAKOLIATTAR, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (05) :1049-1055

[5]

SELMAN JR, 1978, ADV CHEM ENG, V10, P234

[6]

von Karman T, 1921, Z ANGEW MATH MECH, V1, P233

[7]

ZDUNEK AD, 1992, J ELECTROCHEM SOC, V139

[8]

ZDUNEK AD, 1990, THESIS ILLINOIS I TE

← 1 →