A STUDY OF THE BEHAVIOR OF POLY(N-VINYLCARBAZOLE) IN BINARY-MIXTURES OF TETRAHYDROFURAN AND POLY(ETHYLENE GLYCOL) OLIGOMERS

被引：1
|
作者：
CESTEROS, LC [1 ]
VAZQUEZ, Y [1 ]
RABANAL, N [1 ]
KATIME, I [1 ]
机构：
[1] UNIV BASQUE COUNTRY, FAC CIENCIAS,DEPT QUIM FIS,NUEVOS MAT GRP, APARTADO 644, BILBAO, SPAIN
来源：
POLYMER | 1990年 / 31卷 / 10期
关键词：
miscibility; PEG oligomers; PNVK; preferential solvation; total;
D O I：
10.1016/0032-3861(90)90009-N
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In this paper we report studies on poly(N-vinylcarbazole) (PNVK) in binary mixtures of THF (1) and poly(ethylene glycol) (2) obtained by viscometry and laser light scattering measurements. From these data, total and preferential solvation parameters were calculated over the whole binary mixture composition range studied. We have not found any inversion in the solvation. Inter- and intra-molecular interactions, Kθ and B, were calculated using the Stockmayer-Fixman equation. Finally, we found that the compatibility between PNVK and PEG increases linearly as PEG molar mass increases. © 1990.
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页码：1871 / 1876
页数：6
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