ON THE FINE-STRUCTURE OF SHISH-KEBABS IN INJECTION-MOLDED POLYETHYLENE

被引：15

作者：

MARTINEZSALAZAR, J ^{[1
]}

RAMOS, JVG ^{[1
]}

PETERMANN, J ^{[1
]}

机构：

[1] DORTMUND UNIV,LEHRSTUHL WERKSTODTKUNDE,FACHBEREICH CHEM TECH,W-4600 DORTMUND,GERMANY

来源：

INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS | 1993年 / 21卷 / 3-4期

关键词：

SHISH-KEBAB MORPHOLOGY; MOLECULAR CONNECTIVITY; SAXS AT ELEVATED TEMPERATURES;

D O I：

10.1080/00914039308012038

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The fine structure of melt-crystallized shish-kebabs is investigated by means of TEM, SAXS, DSC and RS. In addition to the well known two morphological entities (shish and kebab), a third entity called ''transitional zone'' has been detected by TEM and two independent SAXS maxima. The transitional zone is characterized by a crystal morphology somewhere in between the shish and kebab crystals and a comparatively high connectivity of molecules along those crystals. In situ SAXS experiments at elevated temperatures reveal the change of the size of this zone with crystallization conditions.

引用

页码：111 / 121

页数：11

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