SOLID-STATE H-2 NMR-STUDIES OF GUEST MOLECULAR-DYNAMICS IN THE BENZENETRICARBONYLCHROMIUM-THIOUREA INCLUSION COMPOUND

被引：0
|
作者：
ALIEV, AE [1 ]
HARRIS, KDM [1 ]
GUILLAUME, F [1 ]
机构：
[1] UNIV BORDEAUX 1,CNRS,URA 124,SPECTROSCOPIE MOLEC & CRISTALLINE LAB,F-33405 TALENCE,FRANCE
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 1995年 / 07期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dynamics of the benzene moiety of perdeuterated benzenetricarbonylchromium (eta(6)-C6D6)Cr(CO)(3) guest molecules in their thiourea inclusion compound, investigated by H-2 NMR spectroscopy, are described by in-plane nearest neighbour 2 pi/6 jumps; the activation energy for this motion (20.2 kJ mol(-1) from H-2 NMR lineshape analysis and 19.8 kJ mol(-1) from H-2 NMR spin-lattice relaxation time measurements) is higher than that for the corresponding motion in the pure crystalline phase of perdeuterated benzenetricarbonylchromium.
引用
收藏
页码：294 / 295
页数：2
相关论文
共 50 条
  • [1] DYNAMICS OF BENZENE AND PYRIDINE GUEST MOLECULES IN THEIR TRI-ORTHO-THYMOTIDE INCLUSION-COMPOUNDS - SOLID-STATE H-2 NMR-STUDIES
    ALIEV, AE
    HARRIS, KDM
    MAHDYARFAR, A
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (13): : 2017 - 2026
  • [2] SOLID-STATE NMR-STUDIES OF MOLECULAR-DYNAMICS AND INTERACTIONS IN COLLAGEN-FIBERS
    TORCHIA, DA
    SARKAR, SK
    SULLIVAN, CE
    NIU, CH
    YOUNG, PE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1983, 186 (AUG): : 80 - POLY
  • [3] Solid State NMR Studies of the Bromocyclohexane/Thiourea Inclusion Compound
    Sabine Ternieden
    Klaus Müller
    Journal of inclusion phenomena and molecular recognition in chemistry, 1998, 30 : 289 - 308
  • [4] Solid state NMR studies of the bromocyclohexane/thiourea inclusion compound
    Ternieden, S
    Muller, K
    JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1998, 30 (04) : 289 - 308
  • [5] MOLECULAR-DYNAMICS OF GRAMICIDIN A BY SOLID-STATE NMR
    HUO, S
    LEE, KC
    LAZO, ND
    HU, W
    NORTH, CL
    CROSS, TA
    BIOPHYSICAL JOURNAL, 1994, 66 (02) : A220 - A220
  • [6] SOLID-STATE NMR-STUDIES OF THE MOLECULAR-DYNAMICS AND PHASE-BEHAVIOR OF MIXED-CHAIN PHOSPHATIDYLCHOLINES
    LEWIS, BA
    DASGUPTA, SK
    GRIFFIN, RG
    BIOCHEMISTRY, 1984, 23 (09) : 1988 - 1993
  • [7] SOLID-STATE NMR-STUDIES OF THE MOLECULAR-DYNAMICS AND PHASE-EQUILIBRIA OF MIXED-CHAIN PHOSPHATIDYLCHOLINES
    LEWIS, BA
    DASGUPTA, SK
    GRIFFIN, RG
    BIOPHYSICAL JOURNAL, 1984, 45 (02) : A332 - A332
  • [8] A H-2 NMR-STUDY OF THE MOLECULAR-DYNAMICS OF SOLID CYCLOPENTANE
    MACK, JW
    TORCHIA, DA
    JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (11): : 4207 - 4213
  • [9] PHENYLALANINE RING DYNAMICS BY SOLID-STATE H-2 NMR
    GALL, CM
    DIVERDI, JA
    OPELLA, SJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (17) : 5039 - 5043
  • [10] Solid-State NMR Studies on the Guest Ordering and Dynamics in α,ω-Dibromoalkane/Urea Inclusion Compounds
    X. Yang
    K. Müller
    Applied Magnetic Resonance, 2007, 32 : 407 - 431
12345