MOLYBDENUM ELECTRODEPOSITION FROM LOW-MELTING CHLORIDE BATHS

被引：0

作者：

ARKHIPOV, PA

BARABOSHKIN, AN

VALEEV, ZI

MARTEMYANOVA, ZS

机构：

来源：

SOVIET ELECTROCHEMISTRY | 1990年 / 26卷 / 12期

关键词：

D O I：

暂无

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Molybdenum electrodeposition and -dissolution was studied in molten chlorides with different cation combinations. The ranges of temperature and current density were established within which one can obtain compact, columnar molybdenum coatings. Passivation of the anode by solid electrochemical reaction products was detected in NaCl-KCl-CsCl-MoCl3 electrolytes. In NaCl-KCl-MgCl2-MoCl3 melts at high MoCl3 concentrations, a lower-valent salt is deposited on the cathode together with molybdenum.

引用

页码：1388 / 1392

页数：5

共 19 条

[1] ARKHIPOV PA, 1989, 5TH UR C HIGH TEMP P, P9
[2] ARZHANNIKOV AA, 1981, ALL UNION S SOLID EL, P34
[3] BARABOSHKIN AN, 1972, T I ELECKTROKHIM URA, P87
[4] BARABOSHKIN AN, 1973, TR I ELEKTROKHIM URA, P65
[5] COUCH DE, 1958, T AM I MIN MET ENG, V212, P320
[6] CUMINGS RE, 1966, 6850 BUR MIN REP INV
[7] KIND GE, 1978, PROBL SOVREM KHIM KO, P163
[8] THE ELECTRODEPOSITION OF IMPROVED MOLYBDENUM COATINGS FROM MOLTEN-SALTS BY THE USE OF ELECTROLYTE ADDITIVES
KIPOUROS, GJ
SADOWAY, DR
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1988, 18 (06) : 823 - 830
[9] EVIDENCE FOR A COMPLEX CHLOROMOLYBDATE ION IN A MOLTEN SALT MEDIUM FROM TRANSFERENCE EXPERIMENTS
LAMB, VA
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1970, 117 (10) : 1269 - +
[10] MELLORS GW, 1964, PLATING, V51, P320

← 1 2 →