COBALT(2) COMPLEXES OF 2,3,5,6-TETRAKIS(2-PYRIDYL)PYRAZINE AND 2,4,6-TRIS(2-PYRIDYL)-1,3,5-TRIAZINE

被引：21

作者：

GOODWIN, HA

SYLVA, RN

VAGG, RS

WATTON, EC

机构：

[1] School of Chemistry, University of New South Wales, Kensington, NSW, 2033

[2] School of Chemistry, Macquarie University, North Ryde, NSW

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 08期

关键词：

D O I：

10.1071/CH9691605

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis-ligand cobalt(II) complexes of 2,4,6-tris(2-pyridyl)-1,3,5-triazine and 2,3,5,6.tetrakis(2-pyridyl)pyrazine have been prepared. The conductivities of the complexes in nitromethane solution correspond to values expected for bi-unielectrolytes. The temperature dependence of their magnetism has shown that in some instances there exists a spin-state equilibrium in the metal atom while in others the metal atom is spin-free and Curie-Weiss laws are obeyed. © 1969, CSIRO. All rights reserved.

引用

页码：1605 / &

共 16 条

[1]

COLTON R, 1963, AERER4186 UKAEA REP

[2]

Figgis B., 1960, MODERN COORDINATION, P403

[3] TRIDENTATE CHELATE COMPOUNDS .2. [J].