BARIUM (CRYPTAND 222B)CL2.6H2O

被引：8
作者：
PETTIT, WA [1 ]
BAENZIGER, NC [1 ]
机构：
[1] UNIV IOWA,DEPT CHEM,IOWA CITY,IA 52242
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷
关键词：
D O I：
10.1107/S0108270193009205
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, (4,7,13,16,21,24-hexaoxa-1,10-diaza-5,6-benzobicyclo[8.8.8]hexacos-5-ene)barium dichloride hexahydrate, [BaCl2(Cl2H36N2O6)1.6H2O, the Ba ion is surrounded by the cryptand molecule (222B) with the arm containing the fused benzene-ring substituent bent towards one of the other two cryptand arms, leaving two slightly larger open faces through which two additional water molecules are coordinated, making a total of ten atoms surrounding the Ba atom. The species could be more accurately represented as [Ba(222B)(H2O)2]2+ .2Cl-.4H2O
引用
收藏
页码：221 / 224
页数：4
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