(Adipato-kappa O-2,O ')diaqua[bis(pyridin-2-yl-kappa N)amine]cobalt(II) trihydrate

被引:1
作者
Setifi, Zouaoui [1 ,2 ]
Setifi, Fatima [2 ,3 ]
Smith, Graham [4 ]
El-Ghozzi, Malika [5 ,6 ]
Rouag, Djamil-Azzeddine [2 ]
Avignant, Daniel [5 ,6 ]
Merazig, Hocine [2 ]
机构
[1] Univ 20 Aout 1955 Skikda, Fac Technol, Dept Technol, Skikda 21000, Algeria
[2] Univ Constantine I, Unite Rech Chim Environm & Mol Struct CHEMS, Constantine 25000, Algeria
[3] Univ Ferhat Abbas Setif I, LCIMN, Setif 19000, Algeria
[4] Queensland Univ Technol, Sci & Engn Fac, Brisbane, Qld 4001, Australia
[5] Univ Blaise Pascal, Clermont Univ, Inst Chim Clermont Ferrand, F-63000 Clermont Ferrand, France
[6] CNRS, ICCF, UMR 6296, F-63171 Aubiere, France
关键词
D O I
10.1107/S1600536813012981
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the monomeric title complex, [Co(C6H8O4)(C10H9N3)(H2O)(2)]center dot 3H(2)O, the distorted octahedral CoN2O4 coordination environment comprises two N-atom donors from the bidentate dipyridyldiamine ligand, two O-atom donors from one of the carboxylate groups of the bidentate chelating adipate ligand and two water molecules. In addition, there are three solvent water molecules which are involved in both intra-and inter-unit O-H center dot center dot center dot O hydrogen-bonding interactions, which together with an amine-water N-H center dot center dot center dot O hydrogen bond produce a three-dimensional framework.
引用
收藏
页码:M335 / +
页数:11
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