N-(4-Aminopyrimidin-5-yl)-4-methyl-N-(4-methylphenylsulfonyl)benzene-sulfonamide

被引：2

作者：

Taher, Abu ^{[1
]}

Smith, Vincent J. ^{[1
]}

机构：

[1] Univ Stellenbosch, Dept Chem & Polymer Sci, Private Bag 11, ZA-7602 Stellenbosch, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

基金：

新加坡国家研究基金会;

关键词：

data-to-parameter ratio = 17.6; mean ω(C-C) = 0.004 Å; R factor = 0.046; single-crystal X-ray study; T = 103 K; wR factor = 0.116;

D O I：

10.1107/S1600536812046442

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C18H18N4O4S2, the mean planes passing through the tosyl benzene rings form dihedral angles of 48.42 (9) and 15.1 (1)degrees with the aminopyrimidine ring. In the crystal, molecules associate via N-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds, forming extended hydrogen-bonded sheets that lie parallel to the bc plane. The N-H center dot center dot center dot N hydrogen bonds propagate along the b-axis direction, while the N-H center dot center dot center dot O hydrogen bonds propagate along the c-axis direction.

引用

页码：O3362 / +

页数：10

共 9 条

[1] Molecular graphics: From science to art
Atwood, JL
Barbour, LJ
[J]. CRYSTAL GROWTH & DESIGN, 2003, 3 (01) : 3 - 8
[2] Barbour L.J., 2001, J SUPRAMOL CHEM, V1, P189, DOI DOI 10.1016/S1472-7862(02)00030-8
[3] Bruker, 2009, APEX2 SAINT SADABS
[4] Synthesis of substituted 2,3-Dihydro-1H-2-benzazepines and 1,2-dihydroisoquinolines using an isomerization-ring-closing metathesis strategy:: Scope and limitations
Panayides, Jenny-Lee
Pathak, Rakhi
de Koning, Charles B.
van Otterlo, Willem A. L.
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2007, 2007 (29) : 4953 - 4961
[5] The synthesis of 2-benzazocines using ring-closing metathesis as a key step
Panayides, Jenny-Lee
Pathak, Rakhi
Panagiotopoulos, Helen
Davids, Hajierah
Fernandes, Manuel A.
de Koning, Charles B.
van Otterlo, Willem A. L.
[J]. TETRAHEDRON, 2007, 63 (22) : 4737 - 4747
[6] DEPROTONATION OF PRIMARY AND SECONDARY AMINO GROUPS IN COBALT METALATION OF ORTHO-HYDROXY-ORTHO'-AMINO(OR ALKYLAMINO) AZO DYES OF PHENYLAZONAPHTHALENE TYPE
SCHETTY, G
[J]. HELVETICA CHIMICA ACTA, 1969, 52 (07) : 1796 - &
[7] A short history of SHELX
Sheldrick, George M.
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
[8] N-(2-Aminopyridin-3-yl)-4-methyl-N-(4-methylphenylsulfonyl) benzene-sulfonamide
Taher, Abu
Smith, Vincent J.
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1136 - +
[9] Application of an isomerization-ring-closing metathesis strategy to the synthesis of unsaturated seven-membered, benzo-fused heterocycles containing two heteroatoms
Yadav, Dharmendra B.
Morgans, Garreth L.
Aderibigbe, Blessing A.
Madeley, Lee G.
Fernandes, Manuel A.
Michael, Joseph P.
de Koning, Charles B.
van Otterlo, Willem A. L.
[J]. TETRAHEDRON, 2011, 67 (16) : 2991 - 2997

← 1 →