PHOTOCHEMICAL-REACTION OF HARMALINE .1. ELECTRONIC-SPECTRA

被引:31
作者
BIONDIC, MC
ERRABALSELLS, R
机构
[1] Departamento de Quimica Organica, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1430-Buenos Aires
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 07期
关键词
D O I
10.1039/p29920001049
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Electronic spectra (absorption, excitation and fluorescence spectra) of harmaline in organic solvents have been recorded. The unusual behaviour of this alkaloid has been studied by excited state proton transfer from organic solvents. The effect of the presence of water in the organic media on the electronic spectra and on the prototropic equilibria in the ground and excited singlet states are discussed briefly. Harmine was selected to be used as a model compound.
引用
收藏
页码:1049 / 1058
页数:10
相关论文
共 46 条