ELECTRON PHOTODETACHMENT FROM A DIRAC BUBBLE POTENTIAL - A MODEL FOR THE FULLERENE NEGATIVE-ION C-60(-)

被引:28
作者
LOHR, LL
BLINDER, SM
机构
[1] Department of Chemistry, University of Michigan, Ann Arbor
关键词
D O I
10.1016/0009-2614(92)90055-R
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A model for the fullerene anion C60- is proposed in which the outer electron moves in an attractive deltafunction potential in the shape of a spherical bubble. Exact solutions for this "Dirac bubble potential" were previously worked out. On the basis of this model, the photodetachment cross-section and its angular distribution are computed as functions of photoelectron energy, for the electron in both S-like and P-like bound states. Secondary maxima and minima in the cross section appear at higher energy values, somewhat analogous to the scattering of radiation from a conducting sphere.
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收藏
页码:100 / 108
页数:9
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