THE CRYSTAL-STRUCTURES OF KIESERITE-TYPE COMPOUNDS .1. CRYSTAL-STRUCTURES OF ME(II)SO4 H2O (ME = MN,FE,CO,NI,ZN)

被引：0
作者：
WILDNER, M
GIESTER, G
机构：
来源：
NEUES JAHRBUCH FUR MINERALOGIE-MONATSHEFTE | 1991年 / 07期
关键词：
KIESERITE-TYPE COMPOUNDS; ME(II)SO4; H2O(ME; MN; FE; CO; NI; ZN); CRYSTAL STRUCTURE; CRYSTAL CHEMISTRY;
D O I：
暂无
中图分类号：
P57 [矿物学];
学科分类号：
070901 ;
摘要：
The crystal structures of five hydrothermally synthesized representatives of the kieserite group Me(II)SO4.H2O [szmikite (Me = Mn), szomolnokite (Me = Fe), dwornikite (Me = Ni), gunningite (Me = Zn) and CoSO4.H2O] were refined in space group C2/c using single crystal X-ray data. The positions of the hydrogen atoms were determined for all five compounds - the hydrogen bonding scheme was found to be in accordance to kieserite, MgSO4.H2O. However, there are small but significant differences in the atomic arrangement of kieserite compared to the investigated isotypic transition metal sulfates.
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页码：296 / 306
页数：11
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