SULFUR-DIOXIDE INSERTION REACTIONS IN PHENYLMERCURY CHELATES

被引：5
作者：
PANDIT, SK
GOPINATHAN, S
GOPINATHAN, C
机构：
[1] Inorganic Chemistry Division, National Chemical Laboratory, Poona
来源：
JOURNAL OF THE LESS-COMMON METALS | 1979年 / 65卷 / 02期
关键词：
D O I：
10.1016/0022-5088(79)90113-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Phenylmercury chelates take up one molecule of sulphur dioxide from a medium of liquid sulphur dioxide to form mono insertion products. Phenylmercury chelates of salicylaldehyde, 8-hydroxyquinoline, benzoylphenyl hydroxylamine, substituted benzophenones and some Schiff bases were studied for the sulphur dioxide insertion reaction. IR studies show that the products are O-sulphinates, the insertion taking place between mercury and the phenyl group. © 1979.
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页码：229 / 235
页数：7
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