REACTIONS OF SOME 2-OXO-1,3,2-OXATHIAPHOSPHOLANES AND 2-OXO-1,3,2-PHOSPHORINANES WITH PHOSPHORUS-PENTACHLORIDE

被引：0
|
作者：
NURETDINOVA, ON
NOVIKOVA, VG
机构：
来源：
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 11期
关键词：
2-OXO-1,3,2-OXATHIAPHOSPHOLANES; PHOSPHORINANES; PHOSPHORUS PENTACHLORIDE;
D O I：
10.1007/BF00863385
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
2-Phenoxy- and 2-dialkylamino-2-oxa-1,3,2-oxathiaphospholanes react with PCl5 with ring opening and formation of the corresponding acid chlorides of thiophosphoric acid. Under analogous conditions, 2-phenoxy-2-oxo-1,3,2-oxathiaphosphorinanes do not react with PCl5, while acid chlorides of thiophosphoric acid are formed in low yield along with other products in the reaction of 2-dialkylamino-2-oxo-1,3,2-oxthiaphosphorinanes with PCl5.
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页码：2121 / 2123
页数：3
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