NUCLEOPHILIC ADDITIONS TO PALLADIUM(II)-ACTIVATED C=C BONDS - SYNTHESIS OF CYCLOPALLADATED 8-SUBSTITUTED QUINOLINE DERIVATIVES

被引：16

作者：

DUPONT, J ^{[1
]}

HALFEN, RAP ^{[1
]}

ZINN, FK ^{[1
]}

PFEFFER, M ^{[1
]}

机构：

[1] LAB MET MEDIATED SYNTH, CNRS, URA 416, F-67000 STRASBOURG, FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 484卷 / 1-2期

关键词：

SYNTHESIS; PALLADIUM; CYCLOPALLADATED COMPOUNDS; NUCLEOPHILIC ADDITIONS; METALLACYCLE; ALKENE;

D O I：

10.1016/0022-328X(94)87212-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

8-Vinylquinoline and alpha-methyl-8-vinylquinoline have been prepared in 40-67% overall yield from 8-methyl- and 8-ethyl-quinoline, respectively. These unsaturated compounds undergo nucleophilic addition with carbon and oxygen nucleophiles at the terminal vinyl carbon atom in the presence of Pd-II compounds affording, exclusively, five-membered metallacyclic rings.

引用

页码：C8 / C9

页数：2

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