EVIDENCE FOR GENERATION OF ELECTRONICALLY EXCITED RADICAL ION IN VERY EXOTHERMIC ELECTRON-TRANSFER FLUORESCENCE QUENCHING

被引：47

作者：

KIKUCHI, K

KATAGIRI, T

NIWA, T

TAKAHASHI, Y

SUZUKI, T

IKEDA, H

MIYASHI, T

机构：

[1] Department of Chemistry, Faculty of Science, Tohoku University, Aoba-ku, Sendai, 980, Aoba, Aramaki

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 193卷 / 1-3期

关键词：

D O I：

10.1016/0009-2614(92)85700-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The free radical yield of electron-transfer fluorescence quenching and the effective encounter distance are studied to determine the quenching mechanism in very exothermic region. Evidence for electronically excited radical generation as the primary quenching product is given for the first time.

引用

收藏

页码：155 / 160

页数：6

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