STUDIES ON NOVEL TERPENOID .1. NOVEL MONOTERPENE ALCOHOLS DERIVED FROM THE OXIDATION OF 2(10)-PINENE WITH LEAD-TETRAACETATE

被引：3

作者：

YOKOI, K

MATSUBARA, Y

机构：

[1] Department of Applied Chemistry, Faculty of Science and Technology, Kinki University, Kouiakae

来源：

NIPPON KAGAKU KAISHI | 1979年 / 05期

关键词：

D O I：

10.1246/nikkashi.1979.641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel monoterpene alcohols, l(7),4(8)-p-menthadien-2-yl acetate [6], trans-l(7)-p-menthen-2,8-diyl diacetate [9] and l-p-menthene-7,8-diyl diacetate [10], were obtained by the oxidation of 2(10)-pinene [1] with lead tetraacetate. trans-4(8)-p-Menthen-2-ol [12] and its cis-isomer [13] were obtained in equal amounts by hydrogenation of l(7),4(8)-p-menthadien-2-ol [6a]. l(7)-p-Menthene-2,8-diol [9a] was easily converted into 1(7),8-p-menthadien-2-ol [11]. © 1979, The Chemical Society of Japan. All rights reserved.

引用

页码：641 / 645

页数：5