ORDER PHENOMENA IN AQUEOUS ALCL3 SOLUTIONS

被引：68

作者：

CAMINITI, R ^{[1
]}

LICHERI, G ^{[1
]}

PICCALUGA, G ^{[1
]}

PINNA, G ^{[1
]}

RADNAI, T ^{[1
]}

机构：

[1] HUNGARIAN ACAD SCI,CENT RES INST CHEM,BUDAPEST,HUNGARY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 71卷 / 06期

关键词：

D O I：

10.1063/1.438654

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

X-ray diffraction data of two aqueous solutions of AlCl3 are interpreted using a model in which the Cl- ions have a coordination number of six and the Al(H2O)63+ ions interact with twelve water molecules through short and linear H bonds, the water molecules nearest neighbor to the Al3+ ions having a trigonal orientation. Moreover, evidence is given that such a hydration structure tends to persist even when the total amount of water present in the system is rather small. © 1979 American Institute of Physics.

引用

页码：2473 / 2476

页数：4

共 19 条

[1] PROTON CHEMICAL-SHIFTS OF WATER IN CATIONIC HYDRATION COMPLEXES AND THEIR CONTRIBUTION TO WATER SHIFTS IN ELECTROLYTE SOLUTIONS [J].

AKITT, JW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (01) :42-49

[2] SIGNIFICANCE OF CHANGES IN TEMPERATURE-DEPENDENCE OF PROTON CHEMICAL-SHIFT OF WATER BROUGHT ABOUT BY DISSOLUTION OF ELECTROLYTES [J].

AKITT, JW .

FARADAY DISCUSSIONS, 1977, 64 :102-111

[3] INTERPRETATION OF X-RAY-DIFFRACTION BY AQUEOUS-SOLUTIONS OF ALUMINUM(III) NITRATE AND CHROMIUM(III) NITRATE [J].

BOL, W ;

WELZEN, T .

CHEMICAL PHYSICS LETTERS, 1977, 49 (01) :189-192

[4] GEOMETRY OF O-H...O HYDROGEN-BONDS [J].

BROWN, ID .

ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (JAN1) :24-31

[5] X-RAY-DIFFRACTION STUDY OF MGCL2 AQUEOUS-SOLUTIONS [J].

CAMINITI, R ;

LICHERI, G ;

PICCALUGA, G ;

PINNA, G .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1979, 12 (FEB) :34-38

[6] HYDRATION WATER EXTERNAL WATER INTERACTIONS AROUND CR-3(+) IONS [J].

CAMINITI, R ;

LICHERI, G ;

PICCALUGA, G ;

PINNA, G .

JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (01) :1-4

[7]

CAMINITI R, 1977, REND SEM FS CAGLIA S, V47, P1

[8] REFINEMENT OF ALUM STRUCTURES .I. X-RAY AND NEUTRON DIFFRACTION STUDY OF CSAL(SO4)2.12H2O A BETA ALUM [J].

CROMER, DT ;

KAY, MI ;

LARSON, AC .

ACTA CRYSTALLOGRAPHICA, 1966, 21 :383-&

[9] X-RAY SCATTERING FACTORS COMPUTED FROM NUMERICAL HARTREE-FOCK WAVE FUNCTIONS [J].

CROMER, DT ;

MANN, JB .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :321-&

[10] REVISED PARAMETERS OF ANALYTIC FITS FOR COHERENT AND INCOHERENT SCATTERED X-RAY INTENSITIES OF FIRST 36 ATOMS [J].

HAJDU, F .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1972, 28 (03) :250-&

← 1 2 →