STRUCTURE AND REACTION OF METHYLANTIMONY DIHALIDES AND TESTS FOR PREPARATION OF METHYLANTIMONY

被引：24

作者：

BREUNIG, HJ

DENKER, M

EBERT, KH

机构：

[1] Fachbereich 2 der Universität Bremen, D-28334 Bremen

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 470卷 / 1-2期

关键词：

ANTIMONY; CHROMIUM; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)80151-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

MeSbCl2 (1) and SbCl3 give the adduct MeSbCl2.0.6SbCl3 (1a). MeSbBr2 (2) reacts with NaI to form MeSbI2 (3) and with Cr(CO)5 THF to give Me(Br)2SbCr(CO)5 (4). The crystal structures of 1a, 2 and 4 are reported. Derivatives of methyl antimony are obtained by reaction of 2 or 4 with Mg in tetrahydrofuran.

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页码：87 / 92

页数：6

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