SYNTHESIS AND STRUCTURE OF ANNELATED CARBON RINGS CONTAINING A BRIDGEHEAD TRANSITION-METAL

被引：20

作者：

OCONNOR, JM ^{[1
]}

PU, L ^{[1
]}

CHADHA, R ^{[1
]}

机构：

[1] UNIV CALIF SAN DIEGO,CRYSTALLOG LAB,LA JOLLA,CA 92093

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 05期

关键词：

D O I：

10.1002/anie.199005431

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An iridium atom in a bridgehead position is the most unusual feature of 2, which was obtained in place of the anticipated carbene vinylidene complex upon reaction of 1 with propiolic acid. Equally surprising is the fact that 2 must be regarded as an oxonium system rather than as a carbene, the most obvious resonance alternative. R  CO2CH3. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：543 / 545

页数：3

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