ENANTIOCONTROLLED ROUTE TO NATURAL-PRODUCTS USING CHIRAL EQUIVALENTS OF CYCLOPENTENONE AND CYCLOHEXENONE

被引：72
作者：
OGASAWARA, K
机构：
[1] Pharmaceutical Institute, Tohoku University, Aobayama
来源：
PURE AND APPLIED CHEMISTRY | 1994年 / 66卷 / 10-11期
关键词：
D O I：
10.1351/pac199466102119
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Efficient preparation of two tricyclic dienones, (1) and (2), in both enantiomeric forms has been developed by employing lipase-mediated resolution. A variety of natural products have been synthesized in enantiocontrolled manners by utilizing the former as a chiral equivalent of 2-cyclopentenone (as well as cyclopentadienone) and the latter as a chiral equivalent of 2-cyclohexenone (as well as 2,5-cyclohexadienone).
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页码：2119 / 2122
页数：4
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