ELECTRONIC-STRUCTURE AND SPECTRA OF [RU(NH3)(5)PYZ](2+) AND [(NH3)(5)RU-PYZ-RU(NH3)(5)](4+)

被引：0
|
作者：
SIZOVA, OV
IVANOVA, NV
BARANOVSKII, VI
NIKOLSKII, AB
机构：
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 1994年 / 35卷 / 04期
关键词：
D O I：
10.1007/BF02578352
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The electronic structure and spectra of [Ru(NH3)(5)pyz](2+) and [(NH3)(5)Ru-pyz-Ru(NH3)(5)](4+) are calculated by the INDO (CINDO-E/S) method. Changes in molecular orbitals, charge distributions, and bond order indices of the pyrazine molecule and [Ru(NH3)(5)pyz](2+) complex in the [(NH3)(5)Ru-pyz-Ru(NH3)(5)](4+) binuclear complex are analyzed.
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页码：433 / 442
页数：10
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