STUDIES IN CHEMICAL IONIZATION MASS-SPECTROMETRY .2. I-C4H10 AND NO SPECTRA OF ALKYNES

被引：18

作者：

BUSKER, E

BUDZIKIEWICZ, H

机构：

[1] Institut für Organische Chemie, Universität Köln, D-5000, Greinstraße

来源：

ORGANIC MASS SPECTROMETRY | 1979年 / 14卷 / 04期

关键词：

D O I：

10.1002/oms.1210140412

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The position of the triple bond of n‐alkynes can be determined by the analysis of the relative abundance of the CnH2n−1 ions in the chemical ionization (i‐butane) spectra. However, chemical ionization (NO) spectra where both hydrocarbon and NO‐containing ions are formed in a characteristic manner are more reliable for this purpose. The limitations of the fragmentation rules established earlier for electron impact spectra of alkynes were investigated by examination of additional examples. Copyright © 1979 John Wiley & Sons, Ltd.

引用

页码：222 / 226

页数：5

共 14 条

[1] LOCALIZATION OF ACETYLENIC BONDS BY MASS SPECTROMETRY [J].