INFLUENCE OF LIGAND ENVIRONMENT ON THE PROTONATION REACTIONS OF HYDRAZIDO(2-) COMPLEXES OF MOLYBDENUM AND TUNGSTEN - X-RAY STRUCTURES OF[M(8-QUIN)(NNH2)(PME2PH)3]I(M=MO OR W - 8-QUIN=QUINOLIN-8-OLATE)

被引:13
作者
CHATT, J [1 ]
FAKLEY, ME [1 ]
RICHARDS, RL [1 ]
机构
[1] ROTHAMSTED EXPTL STN,DEPT MOLEC STRUCT,HARPENDEN AL5 2JQ,HERTFORDSHIRE,ENGLAND
关键词
D O I
10.1016/S0022-328X(00)83197-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The complexes [MX2(NNH2)(PMe2Ph)3] (M = Mo or W; X = Cl, Br or I) give ammonia with H2SO4/MeOH, the yield depending upon X. Ammonia is also obtained from [Mo(8-quin)(NNH2)(PMe2Ph)3]I (M = Mo, 8-quin = quinolin-8-olate) but the tungsten analogue gives hydrazine only. Crystal structures of the 8-quin molybdenum and tungsten complexes are reported. © 1979.
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页码:C6 / C8
页数:3
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