NEW C-C BOND FORMATION THROUGH THE NICKEL-CATALYZED ELECTROCHEMICAL COUPLING OF 1,3-ENYNES AND CARBON-DIOXIDE

被引：26
|
作者：
DERIEN, S [1 ]
CLINET, JC [1 ]
DUNACH, E [1 ]
PERICHON, J [1 ]
机构：
[1] UNIV PARIS 11,COORDINAT ORGAN LAB,CNRS,UA 255,ICMO,F-91405 ORSAY,FRANCE
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 424卷 / 02期
关键词：
D O I：
10.1016/0022-328X(92)83151-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of 1,3-enynes has been carboxylated in a nickel-catalysed electrochemical reaction carried out in a single-compartment cell fitted with a consumable magnesium anode. When 2,2'-bipyridine (bipy) or pentamethyldiethylene triamine (PMDTA) are added as the ancillary ligands, an overall hydrocarboxylation of the triple bond occurs through stereoselective cis-addition.
引用
收藏
页码：213 / 224
页数：12
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