MECHANISTIC STUDY OF THE ELECTROCHEMICAL OXIDATION OF SOME AROMATIC-AMINES IN THE PRESENCE OF BASES

被引：19

作者：

ANDRIEUX, CP ^{[1
]}

GALLARDO, I ^{[1
]}

JUNCA, M ^{[1
]}

机构：

[1] UNIV AUTONOMA BARCELONA,UNIDAD QUIM FIS,BARCELONA,SPAIN

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1993年 / 354卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(93)80336-G

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Cyclic voltammetry was used to investigate the mechanism of anodic oxidation of four aromatic amines, together with the effect of the addition of bases (lutidine, sym-collidine, quinuclidine and hydroxide). Without a methoxy substituent in the para position of the phenyl group, the coupling of two radical cations occurs on the addition of weak bases, but a deprotonation is involved in the presence of hydroxide ion. This deprotonation occurs in all cases when a methoxy substituent is present on the phenyl group.

引用

页码：231 / 241

页数：11

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