MECHANISTIC STUDY OF THE ELECTROCHEMICAL OXIDATION OF SOME AROMATIC-AMINES IN THE PRESENCE OF BASES

被引：19

作者：

ANDRIEUX, CP ^{[1
]}

GALLARDO, I ^{[1
]}

JUNCA, M ^{[1
]}

机构：

[1] UNIV AUTONOMA BARCELONA,UNIDAD QUIM FIS,BARCELONA,SPAIN

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1993年 / 354卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(93)80336-G

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Cyclic voltammetry was used to investigate the mechanism of anodic oxidation of four aromatic amines, together with the effect of the addition of bases (lutidine, sym-collidine, quinuclidine and hydroxide). Without a methoxy substituent in the para position of the phenyl group, the coupling of two radical cations occurs on the addition of weak bases, but a deprotonation is involved in the presence of hydroxide ion. This deprotonation occurs in all cases when a methoxy substituent is present on the phenyl group.

引用

页码：231 / 241

页数：11

共 19 条

[1] ANODIC OXIDATION PATHWAYS OF AROMATIC HYDROCARBONS AND AMINES
ADAMS, RN
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1969, 2 (06) : 175 - &
[2] ULTRAMICROELECTRODES FOR FAST ELECTROCHEMICAL KINETICS
ANDRIEUX, CP
HAPIOT, P
SAVEANT, JM
[J]. ELECTROANALYSIS, 1990, 2 (03) : 183 - 193
[3] ANDRIEUX CP, 1991, J ELECTROANAL CHEM, V304, P241
[4] BRINKHAUS KHG, 1984, ACTA CHEM SCAND B, V37, P499
[5] ELECTROCHEMICAL PROPERTIES OF DIPHENYLAMINES AND OXIDATION-PRODUCTS IN ORGANIC MEDIUM .2. PROPERTIES OF 5,10-DIARYL-5,10-DIHYDROPHENAZINES AND TETRAARYLHYDRAZINES
CAUQUIS, G
DELHOMME, H
SERVE, D
[J]. ELECTROCHIMICA ACTA, 1975, 20 (12) : 1019 - 1026
[6] ELECTROACTIVE POLYANILINE FILMS
DIAZ, AF
LOGAN, JA
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1980, 111 (01): : 111 - 114
[7] DEPROTONATION OF TERTIARY AMINE CATION RADICALS - A DIRECT EXPERIMENTAL APPROACH
DINNOCENZO, JP
BANACH, TE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (23) : 8646 - 8653
[8] POLYANILINE - A HISTORICAL SURVEY
GENIES, EM
BOYLE, A
LAPKOWSKI, M
TSINTAVIS, C
[J]. SYNTHETIC METALS, 1990, 36 (02) : 139 - 182
[9] Giumanini A. G., 1980, SYNTHESIS-STUTTGART, V9, P743
[10] ELECTRODIMERIZATION .8. ROLE OF PROTON-TRANSFER REACTIONS IN MECHANISM OF ELECTROHYDRODIMERIZATION FORMAL KINETICS FOR VOLTAMMETRIC STUDIES (LINEAR SWEEP, ROTATING-DISK, POLAROGRAPHY)
NADJO, L
SAVEANT, JM
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1973, 44 (03): : 327 - 366

← 1 2 →