STEREOCHEMICAL COURSE OF THE CATALYTIC REDUCTION AND OF THE ACIDIC ISOMERIZATION OF 14-BETA-STEROIDS - SYNTHESIS OF DELTA-8-14-BETA-STEROIDS AND 8-ALPHA,9-ALPHA,14-BETA-STEROIDS

被引：5

作者：

ANASTASIA, M

FIECCHI, A

GARIBOLDI, P

GALLI, G

机构：

[1] UNIV MILAN,SCH PHARM,APPL BIOCHEM LAB,I-20129 MILAN,ITALY

[2] UNIV MILAN,FAC SCI,ORGAN CHEM LAB,I-20133 MILAN,ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1980年 / 45卷 / 12期

关键词：

D O I：

10.1021/jo01300a061

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：2528 / 2531

页数：4

共 22 条

[1] MECHANISM OF THE HYDROGEN-CHLORIDE CATALYZED ISOMERIZATION OF 5-ALPHA-CHOLEST-8(14)-EN-3-BETA-OL TO 5-ALPHA, 17-BETA-CHOLEST-14-EN-3-BETA-OL - FATE OF THE 17-ALPHA-HYDROGEN ATOM
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[3] SIDE-CHAIN INVERSION OF STEROIDAL OLEFINS PROMOTED BY HYDROGEN-CHLORIDE
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[5] ANASTASIA M, 1978, J CHEM SOC P1, P1138
[6] STEROID ALKALOIDS .177. SYNTHESIS OF TERTIARY AZIDES .7. EFFECT OF CONFIGURATION OF CARBONS C-5 AND C-17 ON INTRODUCTION OF A 14-BETA AZIDE GROUP ONTO DELTA-14 STEROIDS
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[7] SEMIEMPIRICAL DERIVATION OF C-13 NUCLEAR MAGNETIC-RESONANCE CHEMICAL-SHIFTS - HYDROCARBONS, ALCOHOLS, AMINES, KETONES, AND OLEFINS
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[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1977, 55 (15): : 2813 - 2828
[8] BHACCA NS, 1964, APPLICATIONS NMR SPE, P19
[9] ASPECTS OF STEREOCHEMISTRY .4. THE STERIC REQUIREMENT FOR HYDROGEN-CTALYST INDUCED MIGRATION OF THE OLEFINIC BOND
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[10] UNUSUAL BACKBONE REARRANGEMENT - FORMATION OF 5-ALPHA,17-ALPHA-CHOLEST-14-EN-3-BETA-OL ACETATE FROM 5-ALPHA-CHOLEST-8(14)-EN-3-BETA-OL ACETATE
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (13) : 2005 - 2006

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