TOWARD POLYPHOSPHOLES - SYNTHESIS AND STRUCTURE OF AN ALPHA-LINKED QUATERPHOSPHOLE

被引：81

作者：

DESCHAMPS, E ^{[1
]}

RICARD, L ^{[1
]}

MATHEY, F ^{[1
]}

机构：

[1] ECOLE POLYTECH,DCPH,HETEROELEMENTS & COORDINAT LAB,CNRS,URA 1499,F-91128 PALAISEAU,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 11期

关键词：

D O I：

10.1002/anie.199411581

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

By simple bromine–lithium exchange a 2,5‐dibromophosphole is converted into the corresponding 2‐lithio derivative. This opens a new route to difunctionalized biphospholes (which are interesting in their own right as building blocks for synthesis) and to the unprecedented, α‐linked quaterphosphole 1. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1158 / 1161

页数：4

共 8 条

[1]

Bevierre M.-O., 1990, ANGEW CHEM, V102, P672

[2] A 1ST STEP TOWARD THE PHOSPHORUS ANALOGS OF POLYTHIOPHENES [J].

BEVIERRE, MO ;

MERCIER, F ;

RICARD, L ;

MATHEY, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (06) :655-657

[3]

DESCHAMPS E, 1992, B SOC CHIM FR, V129, P486

[4] BARRIERS TO PYRAMIDAL INVERSION AT PHOSPHORUS IN PHOSPHOLES, PHOSPHINDOLES, AND DIBENZOPHOSPHOLES [J].

EGAN, W ;

TANG, R ;

ZON, G ;

MISLOW, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (23) :6205-&

[5] SYNTHESIS OF THE 1ST ALPHA-LINKED QUATERPYRROLE [J].

IKEDA, H ;

SESSLER, JL .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (08) :2340-2342

[6]

LAPORTE F, IN PRESS J AM CHEM S

[7]

MALAR EJP, 1992, J ORG CHEM, V57, P8694

[8] SYNTHESIS AND SOME REACTIONS OF A 2,2'-BIPHOSPHOLYL [J].

MERCIER, F ;

HOLAND, S ;

MATHEY, F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 316 (03) :271-279

← 1 →