ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALPHA-BRANCHED ALDEHYDES

被引：131
|
作者：
KANG, J
LEE, JW
KIM, JI
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 17期
关键词：
D O I：
10.1039/c39940002009
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of diethylzinc with alpha-branched aldehydes in the presence of a catalytic amount of (1R,2S)-(-)-1-phenyl-2-piperidinopropane-1-thiol 1 provided the corresponding secondary alcohols in almost 100% enantiomeric excess.
引用
收藏
页码：2009 / 2010
页数：2
相关论文
共 50 条
  • [11] Catalytic enantioselective addition of diethylzinc to (hetero)aromatic aldehydes
    Lovel, I
    Oehme, G
    Lukevics, E
    APPLIED ORGANOMETALLIC CHEMISTRY, 1998, 12 (07) : 469 - 474
  • [12] Synthesis of Chiral Pyridylphenols for the Enantioselective Addition of Diethylzinc to Aldehydes
    Wu, Pei-Shan
    Chen, Chinpiao
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2012, 59 (06) : 768 - 781
  • [13] CHIRAL OXAZABOROLIDINES AS CATALYSTS FOR THE ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES
    JOSHI, NN
    SREBNIK, M
    BROWN, HC
    TETRAHEDRON LETTERS, 1989, 30 (41) : 5551 - 5554
  • [14] Enantioselective addition of diethylzinc to aldehydes catalyzed by aziridine carbinols
    Wang, Xiaojuan
    Zhao, Wenxian
    Li, Gaowei
    Liu, Guanjun
    Wang, Jin
    Wang, Mincan
    Liu, Lantao
    TETRAHEDRON-ASYMMETRY, 2015, 26 (15-16) : 815 - 820
  • [15] ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES CATALYZED BY CHIRAL HYDROXY AMINAL
    ASAMI, M
    INOUE, S
    CHEMISTRY LETTERS, 1991, (04) : 685 - 688
  • [16] Aziridine sulfides and disulfides as catalysts for the enantioselective addition of diethylzinc to aldehydes
    Braga, AL
    Milani, P
    Paixao, MW
    Zeni, G
    Rodrigues, OED
    Alves, EF
    CHEMICAL COMMUNICATIONS, 2004, (21) : 2488 - 2489
  • [17] Chiral zinc amides as the catalysts for the enantioselective addition of diethylzinc to aldehydes
    Prasad, KRK
    Joshi, NN
    JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (11): : 3770 - 3771
  • [18] COMPLEMENTARY CATALYTIC ASYMMETRIC INDUCTION IN THE ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES
    SOAI, K
    OOKAWA, A
    OGAWA, K
    KABA, T
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (06) : 467 - 468
  • [19] Enantioselective addition of diethylzinc to aldehydes in the presence of chiral aprotic ligands
    Jin, MJ
    Kim, YM
    Lee, KS
    TETRAHEDRON LETTERS, 2005, 46 (15) : 2695 - 2696
  • [20] Chiral pyrrolidine derivatives as catalysts in the enantioselective addition of diethylzinc to aldehydes
    Yang, XW
    Shen, JH
    Da, CS
    Wang, R
    Choi, MCK
    Yang, LW
    Wong, KY
    TETRAHEDRON-ASYMMETRY, 1999, 10 (01) : 133 - 138
12345