ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALPHA-BRANCHED ALDEHYDES

被引：131

作者：

KANG, J

LEE, JW

KIM, JI

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 17期

关键词：

D O I：

10.1039/c39940002009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of diethylzinc with alpha-branched aldehydes in the presence of a catalytic amount of (1R,2S)-(-)-1-phenyl-2-piperidinopropane-1-thiol 1 provided the corresponding secondary alcohols in almost 100% enantiomeric excess.

引用

页码：2009 / 2010

页数：2

共 19 条

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