ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALPHA-BRANCHED ALDEHYDES

被引：131
|
作者：
KANG, J
LEE, JW
KIM, JI
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 17期
关键词：
D O I：
10.1039/c39940002009
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of diethylzinc with alpha-branched aldehydes in the presence of a catalytic amount of (1R,2S)-(-)-1-phenyl-2-piperidinopropane-1-thiol 1 provided the corresponding secondary alcohols in almost 100% enantiomeric excess.
引用
收藏
页码：2009 / 2010
页数：2
相关论文
共 50 条
  • [1] Salicylhydrazone ligands for enantioselective addition of diethylzinc to aldehydes
    Arai, Takayoshi
    Endo, Yoko
    Yanagisawa, Akira
    TETRAHEDRON-ASYMMETRY, 2007, 18 (02) : 165 - 169
  • [2] ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES CATALYZED BY PYRIDINEOXAZOLINEALCOHOLS
    MACEDO, E
    MOBERG, C
    TETRAHEDRON-ASYMMETRY, 1995, 6 (02) : 549 - 558
  • [3] ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES CATALYZED BY ALPHA-AMINO-ACID AMIDES
    MORI, A
    YU, DH
    INOUE, S
    SYNLETT, 1992, (05) : 427 - 428
  • [4] RETROPINACOLIN REARRANGEMENT OF ACYLOXYCARBOCATIONS FROM ALPHA-BRANCHED ALDEHYDES
    LUKYANOV, SM
    BORODAEV, SV
    BORODAEVA, SV
    ZHURNAL ORGANICHESKOI KHIMII, 1983, 19 (10): : 2154 - 2158
  • [5] Aziridino alcohols as catalysts for the enantioselective addition of diethylzinc to aldehydes
    Tanner, D
    Korno, HT
    Guijarro, D
    Andersson, PG
    TETRAHEDRON, 1998, 54 (47) : 14213 - 14232
  • [6] CHIRAL PIPERAZINES AS CATALYSTS FOR THE ENANTIOSELECTIVE ADDITION OF DIETHYLZINC TO ALDEHYDES
    FUJI, K
    TANAKA, K
    MIYAMOTO, H
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1993, 41 (09) : 1557 - 1561
  • [7] Vasicine as tridentate ligand for enantioselective addition of diethylzinc to aldehydes
    Aga, Mushtaq A.
    Kumar, Brijesh
    Rouf, Abdul
    Shah, Bhahwal A.
    Taneja, Subhash C.
    TETRAHEDRON LETTERS, 2014, 55 (16) : 2639 - 2641
  • [8] Enantioselective addition of diethylzinc to aldehydes catalyzed by fluorous β-aminoalcohols
    Nakamura, Y
    Takeuchi, S
    Okumura, K
    Ohgo, Y
    TETRAHEDRON, 2001, 57 (26) : 5565 - 5571
  • [9] Enantioselective addition of diethylzinc to aldehydes catalyzed by chiral hydroxymethylthiazolidines
    Kim, SH
    Chung, ST
    Jin, MJ
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 1998, 4 (04) : 345 - 347
  • [10] Enantioselective addition of diethylzinc to aromatic aldehydes with aminophenol as catalysts
    Li, XS
    Shen, ZX
    Ge, JF
    Zhang, YW
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2003, 23 (04) : 387 - 389
12345