OXIDATION OF ALCOHOLS BY MOLYBDENUM AND TUNGSTEN PEROXO COMPLEXES

被引：171

作者：

JACOBSON, SE

MUCCIGROSSO, DA

MARES, F

机构：

[1] Allied Chemical Corporation, Corporate Research Center, Morristown

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 06期

关键词：

D O I：

10.1021/jo01320a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It has been demonstrated that peroxo complexes of molybdenum and tungsten oxidize secondary alcohols to ketones. The best yields have been obtained with hydrogen oxodiperoxo(pyridine-2-carboxylato)mo!ybdate(VI) and its tungsten analogue. The latter complex proved to be a good catalyst for oxidation of secondary alcohols to ketones by hydrogen peroxide. The kinetics of the catalytic oxidation are reported, and a mechanism of the reaction is suggested. © 1979, American Chemical Society. All rights reserved.

引用

页码：921 / 924

页数：4