OXIDATION OF ALCOHOLS BY MOLYBDENUM AND TUNGSTEN PEROXO COMPLEXES

被引：171
作者：
JACOBSON, SE
MUCCIGROSSO, DA
MARES, F
机构：
[1] Allied Chemical Corporation, Corporate Research Center, Morristown
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 06期
关键词：
D O I：
10.1021/jo01320a006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
It has been demonstrated that peroxo complexes of molybdenum and tungsten oxidize secondary alcohols to ketones. The best yields have been obtained with hydrogen oxodiperoxo(pyridine-2-carboxylato)mo!ybdate(VI) and its tungsten analogue. The latter complex proved to be a good catalyst for oxidation of secondary alcohols to ketones by hydrogen peroxide. The kinetics of the catalytic oxidation are reported, and a mechanism of the reaction is suggested. © 1979, American Chemical Society. All rights reserved.
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页码：921 / 924
页数：4
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