STEREOSELECTIVE ELECTROCHEMICAL SYNTHESIS OF SILYL ENOL ETHERS USING A SACRIFICIAL MAGNESIUM ANODE

被引：27

作者：

BONAFOUX, D ^{[1
]}

BORDEAU, M ^{[1
]}

BIRAN, C ^{[1
]}

DUNOGUES, J ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CHIM ORGAN & ORGANOMET LAB,CNRS,URA 35,F-33405 TALENCE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

SILYL ENOL ETHERS; STEREOSELECTIVE SYNTHESIS; ELECTROGENERATED BASES; SACRIFICIAL MAGNESIUM ANODE;

D O I：

10.1016/0022-328X(94)05368-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 2-pyrrolidone magnesium salt electrogenerated in an undivided cell fitted with a sacrificial magnesium anode allowed the stereoselective synthesis of Z-silyl enol ethers upon deprotonation of enolizable ketones in the presence of a complexing agent.

引用

页码：27 / 32

页数：6

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