CYANOSILYLATION OF A MOLYBDENUM(VI) DIOXO COMPLEX

被引:22
作者
ARZOUMANIAN, H
CORAO, C
KRENTZIEN, H
LOPEZ, R
TERUEL, H
机构
[1] CENT UNIV VENEZUELA, CARACAS, VENEZUELA
[2] UNIV SIMON BOLIVAR, CARACAS, VENEZUELA
关键词
D O I
10.1039/c39920000856
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dioxobis(N,N-diethyldithiocarbamato)molybdenum(VI) reacts with trimethylcyanosilane in a 1 : 1 ratio to give a stable adduct which is fully characterized by X-ray analysis.
引用
收藏
页码:856 / 858
页数:3
相关论文
共 17 条
[1]   OXYGEN ATOM TRANSFER IN DIALKYLDIOXO-MOLYBDENUM OR DIALKYLDIOXO-TUNGSTEN COMPLEXES - A CASE OF DIALKYLDIOXO-ALKYLALKYLIDENEOXOHYDROXOMETAL TAUTOMERISM [J].
ARZOUMANIAN, H ;
KRENTZIEN, H ;
TERUEL, H .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (01) :55-56
[2]   ORGANOMETALLIC COMPOUNDS CONTAINING OXYGEN-ATOMS [J].
BOTTOMLEY, F ;
SUTIN, L .
ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1988, 28 :339-396
[3]  
Griffith W. P., 1970, COORDINATION CHEM RE, V5, P459
[4]  
HABER J, 1980, KINET CATAL+, V21, P100
[6]   METAL-CENTERED OXYGEN ATOM TRANSFER-REACTIONS [J].
HOLM, RH .
CHEMICAL REVIEWS, 1987, 87 (06) :1401-1449
[7]   ENANTIOSELECTIVE ADDITION-REACTION OF TRIMETHYLSILYL CYANIDE WITH ALDEHYDES USING A CHIRAL TIN(II) LEWIS ACID [J].
KOBAYASHI, S ;
TSUCHIYA, Y ;
MUKAIYAMA, T .
CHEMISTRY LETTERS, 1991, (04) :541-544
[8]   MOLECULAR-COMPLEXES FOR EFFICIENT METATHESIS OF OLEFINS - THE OXO-LIGAND AS A CATALYST-COCATALYST BRIDGE AND THE NATURE OF THE ACTIVE SPECIES [J].
KRESS, J ;
WESOLEK, M ;
LENY, JP ;
OSBORN, JA .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (20) :1039-1040
[9]   YTTERBIUM TRICYANIDE, A HIGHLY EFFICIENT CATALYST FOR THE ADDITION OF CYANOTRIMETHYLSILANE TO CARBONYL-COMPOUNDS [J].
MATSUBARA, S ;
TAKAI, T ;
UTIMOTO, K .
CHEMISTRY LETTERS, 1991, (08) :1447-1450
[10]   DIALKYLDITHIOCARBAMATE COMPLEXES OF MOLYBDENUM(V) AND MOLYBDENUM(6) [J].
MOORE, FW ;
LARSON, ML .
INORGANIC CHEMISTRY, 1967, 6 (05) :998-&