SOLUBILITY OF AROMATIC HYDROCARBONS IN AQUEOUS SOLUTIONS OF COMPLEX ION ELECTROLYTES

被引：17
作者：
MASTERTON, WL
LEE, TP
BOYINGTO.RL
机构：
[1] Department of Chemistry, University of Connecticut, Storrs, CT
来源：
JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 08期
关键词：
D O I：
10.1021/j100842a052
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Benzene, naphthalene, and phenanthrene are salted in by salts containing the trans-[Co(en)2NCSCl]+ cation. Since the extent of salting in increases with the polarizability of both the anion and the hydrocarbon molecule, dispersion forces appear to play a major role. The Setschenow parameters can be fitted in a semiempirical manner to the equation of Bockris, et al.; the McDevit-Long equation is less successful.
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页码：2761 / +
页数：1
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