SOLUBILITY OF AROMATIC HYDROCARBONS IN AQUEOUS SOLUTIONS OF COMPLEX ION ELECTROLYTES

被引：17

作者：

MASTERTON, WL

LEE, TP

BOYINGTO.RL

机构：

[1] Department of Chemistry, University of Connecticut, Storrs, CT

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 08期

关键词：

D O I：

10.1021/j100842a052

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Benzene, naphthalene, and phenanthrene are salted in by salts containing the trans-[Co(en)2NCSCl]+ cation. Since the extent of salting in increases with the polarizability of both the anion and the hydrocarbon molecule, dispersion forces appear to play a major role. The Setschenow parameters can be fitted in a semiempirical manner to the equation of Bockris, et al.; the McDevit-Long equation is less successful.

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页码：2761 / +

页数：1

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