Initial Stage in the Low-Temperature Oxidation of Coal in Air

被引：7

作者：

Butakova, V. I. ^{[1
]}

Popov, V. K. ^{[1
]}

Posokhov, Yu. M. ^{[1
]}

Kuznetsova, N. P. ^{[2
]}

机构：

[1] OAO VUKhIN, Ekaterinburg, Russia

[2] OAO Uralskaya Stal, Novotroitsk, Russia

来源：

COKE AND CHEMISTRY | 2013年 / 56卷 / 07期

关键词：

low-temperature oxidation; molecular mechanism; radical-chain process; coal;

D O I：

10.3103/S1068364X13070028

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The main chemical reactions during the initial stage of low-temperature coal oxidation in air are discussed. The contribution of these reactions to the overall oxidative process is determined by the coal structure. Water molecules may accelerate coal oxidation by the formation of aldehyde fragments that react with molecular oxygen by a radical-chain reaction, to produce acidic structures. However, they may also slow the reaction of oxygen with coal by screening the active centers.

引用

页码：225 / 234

页数：10

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