PHOTOCATALYTIC CLEAVAGE OF 1,2-DIOLS BY A COFACIALLY HINDERED WATER-SOLUBLE IRON(III) PORPHYRIN

被引：33

作者：

ITO, Y

KUNIMOTO, K

MIYACHI, S

KAKO, T

机构：

[1] Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Kyoto

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 32期

关键词：

D O I：

10.1016/0040-4039(91)80613-B

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photocatalytic decompositions of 1,2-diols by newly synthesized [meso-tetrakis(3,5-dichloro-1-methyl-4-pyridiniumyl)porphyrinato]iron(III) Fe(III)TCl2MPyP were compared with those by [meso-tetrakis(1-methyl-4-pyridiniumyl)prophyrinato]iron(III) Fe(III)TMPyP. Cofacially hindered FeTCl2MPyP was more robust and substrate-specific than FeTMPyP.

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页码：4007 / 4010

页数：4

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