DESULFURIZATION OF THIOANILIDES VIA PALLADIUM COMPLEXES

被引：6

作者：

ALPER, H

CURRIE, JK

机构：

[1] Department of Chemistry, University of Ottawa, Ottawa

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 168卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)83218-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thioanilides (ArNHCSR) react with disodium tetrachloropalladate at room temperature to give bidentate complexes of structural type [(ArNC(R)S)PdCl]2. These complexes are quantitatively converted to amides by wet dimethylsulphoxide at room temperature. The desulphurization of thioanilides can be effected catalytically as well. © 1979.

引用

收藏

页码：369 / 373

页数：5

相关论文

共 7 条

[1] ORTHO-METALATION OF FERROCENE [J].

ALPER, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 80 (02) :C29-C30

[2] IRON CARBONYL-COMPLEXES OF THIOUREAS AND THIOAMIDES [J].

ALPER, H ;

CHAN, ASK .

INORGANIC CHEMISTRY, 1974, 13 (01) :225-232

[3] CHEMISTRY OF SULFUR-DONOR LIGAND ORTHO-METALATED IRON CARBONYL-COMPLEXES AND THIOLACTONES DERIVED THEREFROM [J].

ALPER, H ;

ROOT, WG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (15) :4251-4257

[4] CYCLOMETALATION REACTIONS [J].

BRUCE, MI .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (02) :73-86

[5] 6-MEMBERED ORTHO-METALLATED RING-SYSTEMS [J].

CAMERON, ND ;

KILNER, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (16) :687-688

[6] REACTIVITY OF COORDINATED LIGANDS .15. FORMATION OF COMPLEXES CONTAINING GROUP V DONOR ATOMS AND METAL-CARBON SIGMA BONDS [J].

COCKBURN, BN ;

HOWE, DV ;

KEATING, T ;

JOHNSON, BFG ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (04) :404-410

[7] REACTIVITY OF CYCLOPALLATATED COMPOUNDS .3. REACTION WITH GROUP V DONOR ATOMS LIGANDS [J].

DEHAND, J ;

PFEFFER, M ;

ZINSIUS, M .

INORGANICA CHIMICA ACTA, 1975, 13 (03) :229-232