PENTACARBONYLIODOMANGANESE(I)

被引：5

作者：

BLAKE, AJ

JOHNSON, BFG

SIEKER, A

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270192005559

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecules of Mn(CO)5I occupy sites of mm (C2v) symmetry with the iodine, manganese and one carbonyl on the twofold axis. The Mn-I distance is 2.6940 (8) angstrom and the Mn-C distances are inequivalent, that trans to iodine being shorter by 0.043 (9) angstrom. The four equivalent carbonyl ligands are bent from coplanarity with the metal by 0.102 (4) angstrom in the direction of the iodine.

引用

页码：1708 / 1709

页数：2

共 7 条

[1] FASTER DATA-COLLECTION WITHOUT LOSS OF PRECISION - AN EXTENSION OF THE LEARNT PROFILE METHOD [J].

CLEGG, W .

ACTA CRYSTALLOGRAPHICA SECTION A, 1981, 37 (JAN) :22-28

[2] A NITROGEN-GAS-STREAM CRYOSTAT FOR GENERAL X-RAY-DIFFRACTION STUDIES [J].

COSIER, J ;

GLAZER, AM .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1986, 19 (02) :105-107

[3] THE STRUCTURE OF RHENIUM PENTACARBONYL CHLORIDE, RE(CO)5CL [J].

COTTON, FA ;

DANIELS, LM .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1983, 39 (NOV) :1495-1496

[4]

Couldwell M. C., 1977, CRYST STRUCT COMMUN, V6, P1

[5]

FACKLER JP, 1992, ACTA CRYSTALLOGR C, V48, P908

[6] CRYSTAL AND MOLECULAR STRUCTURE OF CHLOROPENTACARBONYLMANGANESE [J].

GREENE, PT ;

BRYAN, RF .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (10) :1559-&

[7]

SHELDRICK GM, 1990, SHELXTL PLUS PC VERS

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