A GENERAL-SYNTHESIS OF BETA-HYDROXY ACYLSILANES, ALPHA,BETA-UNSATURATED ACYLSILANES, AND BETA-OXO ACYLSILANES - APPLICATION TO THE SYNTHESIS OF SUGAR DERIVED ACYLSILANES

被引：0

作者：

PLANTIERROYON, R ^{[1
]}

PORTELLA, C ^{[1
]}

机构：

[1] UFR SCI,CNRS,REARRANGEMENTS THERM & PHOTOCHIM LAB,BP 347,F-51062 REIMS,FRANCE

来源：

SYNLETT | 1994年 / 07期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report a convenient method for synthesis of functionnalized acylsilanes (beta-hydroxy, alpha,beta-unsaturated and beta-oxo-acylsilanes) from epoxides and 2-lithio-2-trimethylsilyl-1,3-dithiane. This method was adapted to 5,6-anhydro-D-glucose derivative to prepare various glucose derived acylsilanes.

引用

页码：527 / 529

页数：3

共 20 条

[1] BERNARDI R, 1987, J ORG CHEM, V52, P5022
[2] SYNTHESIS OF SILYL AND GERMYL KETONES
BROOK, AG
DUFF, JM
NONES, PF
DAVIS, NR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (02) : 431 - &
[3] DIASTEREOSELECTIVITY IN NUCLEOPHILIC-ADDITION REACTIONS TO (ALPHA-BETA-DIALKOXYACYL)SILANES - AN OPERATIONALLY USEFUL ROUTE TO OPTICALLY-ACTIVE 1,2,3-SYN-TRIOLS
CIRILLO, PF
PANEK, JS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (25) : 6071 - 6073
[4] SYNTHESIS OF ALPHA-SILYL KETONES VIA 1,3-DITHIANES
COREY, EJ
SEEBACH, D
FREEDMAN, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (02) : 434 - &
[5] DEGL'INNOCENTI A, 1992, SYNLETT, P332
[6] DONDY B, 1992, SYNTHESIS-STUTTGART, P995
[7] MIXED ORGANOFLUORINE-ORGANOSILICON CHEMISTRY .3. A HIGHLY EFFICIENT AND CONVENIENT SYNTHESIS OF ARYL PERFLUORALK-1-ENYL KETONES FROM PERFLUOROALKYL IODIDES AND AROYLSILANES
DONDY, B
PORTELLA, C
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (24) : 6671 - 6674
[8] MIXED ORGANOFLUORINE-ORGANOSILICON CHEMISTRY .4. PERFLUOROENOXYSILANES - SYNTHESIS AND REACTIVITY
DOUSSOT, P
PORTELLA, C
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (24) : 6675 - 6680
[9] EMERSON DW, 1971, TETRAHEDRON LETT, V12, P3445
[10] ACYCLIC STEREOSELECTION .7. STEREOSELECTIVE SYNTHESIS OF 2-ALKYL-3-HYDROXY CARBONYL-COMPOUNDS BY ALDOL CONDENSATION
HEATHCOCK, CH
BUSE, CT
KLESCHICK, WA
PIRRUNG, MC
SOHN, JE
LAMPE, J
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (06) : 1066 - 1081

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