NEW SPECTROSCOPY OF WATER USING TUNABLE PICOSECOND PULSES IN THE INFRARED

被引：203

作者：

GRAENER, H

SEIFERT, G

LAUBEREAU, A

机构：

[1] Physikalisches Institut, Universität Bayreuth

来源：

PHYSICAL REVIEW LETTERS | 1991年 / 66卷 / 16期

关键词：

D O I：

10.1103/PhysRevLett.66.2092

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Spectral hole burning is observed for the OH stretching mode of HDO dissolved in D2O at 298 K after intense infrared excitation. Three spectral components are inferred from the transient band shapes and related to an icelike molecular environment and other hydrogen-bonding configurations. A population lifetime of T1 = 8 +/- 2 ps and an anharmonic frequency shift of 270 +/- 20 cm-1 are measured.

引用

页码：2092 / 2095

页数：4