SPIN-ORBIT-COUPLING IN MOLECULAR AUGER-SPECTRA - PROPENSITY RULES TESTED FOR WATER

被引：13

作者：

AGREN, H

VAHTRAS, O

机构：

[1] Institute of Physics and Measurement Technology, University of Linkoping, Linkoping

来源：

JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS | 1993年 / 26卷 / 05期

关键词：

D O I：

10.1088/0953-4075/26/5/014

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Electronic spectra of dicationic molecules comprise a high density of singlet and triplet states. By virtue of simple propensity rules only the singlet states are selected by core-valence (CVV) Auger spectroscopy. We use second-order response theory to explore the role of spin-orbit interaction in the manifold of low-lying dicationic states and its implications on the intensity analysis of the Auger spectrum of water.

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页码：913 / 919

页数：7

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