HYDROGEN TRANSFER-REACTIONS .18. THE CIS SELECTIVITY IN DEHYDROGENATION BY QUINONES

被引：3

作者：

WEHAGE, H ^{[1
]}

HEESING, A ^{[1
]}

机构：

[1] UNIV MUNSTER,INST ORGAN CHEM,ORLEANS RING 23,W-4400 MUNSTER,GERMANY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 11期

关键词：

HYDROGEN TRANSFER; AROMATIZATION; STEREOSELECTIVITY; QUINONES;

D O I：

10.1002/cber.19911241138

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In contrast to literature results the dehydrogenation of [cis-5,6-D2]-1,3-cyclohexadiene by o-chloranile proceeds stereo-selectively. Fast 1,5-hydrogen shifts in the last pyrolytic step of the synthesis are the cause of the contrary report.

引用

页码：2629 / 2631

页数：3

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