CATALYTIC METHYLALUMINUM DICHLORIDE - AN EFFICIENT METHOD FOR ACCELERATING THE INTRAMOLECULAR DIELS-ALDER REACTION OF THE FURAN DIENE

被引：36
作者：
ROGERS, C [1 ]
KEAY, BA [1 ]
机构：
[1] UNIV CALGARY,CALGARY T2N 1N4,ALBERTA,CANADA
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 45期
关键词：
INTRAMOLECULAR DIELS-ALDER REACTION; FURAN; METHYLALUMINUM DICHLORIDE; CATALYST;
D O I：
10.1016/0040-4039(91)80197-E
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Catalytic (10 mol%) methylaluminum dichloride was found to be an efficient catalyst for the intramolecular Diels-Alder reaction of the furan diene providing oxatricyclo adducts at -65-degrees-C within two hours in yields ranging from good to excellent.
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页码：6477 / 6480
页数：4
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