GENERAL METHOD OF SYNTHESIS AND ISOLATION, AND AN NMR-SPECTROSCOPIC STUDY, OF "TETRA-O-ACETYL-D-ALDOPENTOFURANOSES

被引：93

作者：

KAM, BL ^{[1
]}

BARASCUT, JL ^{[1
]}

IMBACH, JL ^{[1
]}

机构：

[1] UNIV MONTPELLIER 2,CHIM BIOORGAN LAB,F-34060 MONTPELLIER,FRANCE

来源：

CARBOHYDRATE RESEARCH | 1979年 / 69卷 / MAR期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0008-6215(00)85758-4

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The Guthrie-Smith method for the synthesis of tetra-O-acetyl-β-d-ribofuranose has been successfully generalized to apply to the d-aldopentofuranose series. Treament of a d-aldopentose with acidic methanol, followed by acetylation and acetolysis, led to the peracetylated derivatives in good yields. All compounds were characterized, and their structures established. Isolation of products is described, and their 1H- and 13C-n.m.r. spectra are discussed. © 1979.

引用

页码：135 / 142

页数：8

共 22 条

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