Collision induced electronic transitions of oxygen

被引：31

作者：

Rettschnick, R. P. H. ^{[1
]}

Hoytink, G. J.

机构：

[1] Univ Amsterdam, Phys Chem Lab, NL-1012 WX Amsterdam, Netherlands

[2] Univ Sheffield, Dept Chem, Sheffield, S Yorkshire, England

来源：

CHEMICAL PHYSICS LETTERS | 1967年 / 1卷 / 04期

关键词：

D O I：

10.1016/0009-2614(67)85011-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is shown that the collision induced spin and symmetry forbidden transitions of the oxygen molecule are due to electron exchange between two oxygen molecules during collision. Due to this exchange the forbidden transitions borrow intensity from allowed electric dipole transitions, particularly the Schumann-Runge transitions. The simultaneous electronic transitions of the collision complex can be explained by the same mechanism.

引用

页码：145 / 148

页数：4

共 31 条

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