CLEAVAGE OF THE C-SE BOND OF CYCLIC SELENOACETALS DERIVED FROM 4-T-BUTYL CYCLOHEXANONE WITH BUTYLLITHIUMS AND TIN AND SILYL HYDRIDES

被引：20

作者：

KRIEF, A

BADAOUI, E

DUMONT, W

机构：

[1] Department of Chemistry, Facultés Universitaires Notre-Dame de la Paix, B-5000 Namur

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(00)61373-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selenoacetals derived from 1,3-propanediselenol and 1,2-ethanediselenol are much less Hone to be cleaved by butyllithiums than their open chain analogues. The stereochemistry of the products resulting from these reactions as well as from the cleavage of the C-Se bond under radical conditions is disclosed.

引用

页码：8517 / 8520

页数：4

共 4 条

[1] SYNTHESIS OF SELENOACETALS [J].